Networks
Abruña, Héctor D
Positions
- Affiliations
- Research
- Publications
- Teaching
- Background
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Affiliations
member of graduate field
other Cornell affiliations
member of
- David R. Atkinson Center for a Sustainable Future (ACSF) Faculty Fellow
Research
research overview
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Our research effort takes an interdisciplinary approach to the study of electrochemical phenomena. We employ electrochemical techniques as probes of a variety of chemical systems, and we use other techniques such as x-ray based methods, differential electrochemical mass spectrometry, in-situ FT-IR, scanned probe microscopies, scanning electrochemical microscopy, low temperature conductance and spectroscopic techniques to address problems of electrochemical interest. Current areas of research include:
1. Fuel cells:
• The use of ordered intermetallics, such as BiPt for the electrocatalytic oxidation of formic acid, methanol, ethanol and other small organic molecules of potential utility as fuels in fuel cells.
• Use of Differential Electrochemical Mass Spectrometry (DEMS), in-situ FT-IR in for mechanistic studies related to fuel cells.
• Development of in-situ TEM techniques for the study of fuel cell and battery materials
2. Electrical Energy Storage (EES): Batteries and Supercapacitors
• Computational screening synthesis and characterization of organic molecules for EES
• In-situ testing of battery systems using in-situ x-ray based technique (XRD, EXAFS, XANES)
• Lithium/sulfur batteries
3. Molecular electronics:
• The synthesis of nanometric building blocks and their use in molecular electronic devices.
• Transport measurements using mechanical break junctions and break junctions made through electromigration
• Investigations of graphene as an experimental electrochemical platform
• Surface diffusion and surface dynamics on single-layer graphene using scanning electrochemical microscopy.
principal investigator on
- CCI PHASE I: CENTER FOR MOLECULAR INTERFACING awarded by DIRECTORATE FOR MATHEMATICAL & PHYSICAL SCIENCES NSF 2008 - 2012
- DEVELOPMENT OF MATERIALS FOR IMPROVED LITHIUM ION BATTERY ELECTRODES FOR AUTOMOTIVE APPLICATIONS awarded by NEW YORK STATE ENERGY RESEARCH AND DEVELOPMENT AUTHORITY 2011 - 2012
- DISCOVER AND DEVELOPMENT OF NEW MATERIALS FOR LITHIUM SULFIDE BASED BATTERIES FOR AUTOMOTIVE APPLICATIONS awarded by FUJI HEAVY INDUSTRIES 2007 - 2012
- ENERGY MATERIALS CENTER AT CORNELL (EMC2) ENERGY R&D ACCELERATION PROGRAM (ERAP) FOR NYS BUSINESSES awarded by NEW YORK STATE ENERGY RESEARCH AND DEVELOPMENT AUTHORITY 2010 - 2014
- NANOSTRUCTURED INTERFACES FOR ENERGY GENERATION, CONVERSION AND STORAGE awarded by WASHINGTON-HEADQUARTERS DOE 2009 - 2014
- NEW MOLECULAR PLATFORMS AND ARCHITECTURES FOR ELECTRICAL ENERGY STORAGE awarded by LOCKHEED MARTIN CORPORATION 2008 - 2012
- TRANSPORT PHENOMENA AND INTERFACIAL KINETICS IN PLANAR MICROFLUIDIC MEMBRANELESS FUEL CELLS: BASIC RESEARCH FOR THE HYDROGEN FUEL INITIATIVE awarded by DEPARTMENT OF ENERGY 2005 - 2012
keywords
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Electrochemistry, molecular electronics, fuel cells, batteries, electrocatalysis
Publications
individual publications
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academic article
- Tailored Redox Functionality of Small Organics For Pseudocapacitive Electrodes. Energy and Environmental Science. 7176-7187. 2012
- Integration of Self-Assembled Redox Molecules in Flash Memory Devices. IEEE Transactions on Electron Devices. 58:826-834. 2011
- Integration of Self-assembled Redox Molecules in Flash Memories. IEEE Transactions on Electron Devices. 58:826-834. 2011
- Silver delafossite nitride, AgTaN2?. Journal of Solid State Chemistry. 184:7-11. 2011
- Mechanisms of quenching of alexa fluorophores by natural amino acids. Journal of the American Chemical Society. 132:7244-7245. 2010
- Pt-Decorated PdCo @ Pd/C Core-shell Nanoparticles with enhanced stability and Electrocatalytic Activity for the Oxygen Reduction Reaction. Journal of the American Chemical Society. 132:17664-17666. 2010
- Theoretical and electrochemical analysis of poly(3,4-alkylenedioxythiophenes): Electron-donating effects and onset of p-doped conductivity. The Journal of Physical Chemistry C. 114. 2010
- Electron injection from colloidal PbS quantum dots into titanium dioxide nanoparticles. Acs Nano. 2:2206-2212. 2008
- Polymer Brushes as Responsive Materials for the Biology-Material Interface. Polymeric Materials: Science & Engineering. 99:109-110. 2008
- Probing Electrostatic Potentials in Solution with Carbon Nanotube Transistors. Nano Letters. 6:1329-1333. 2006
- Determination of spatial distributions of zinc and active biomass in microbial biofilms by two-photon laser scanning microscopy. Applied Environmental Microbiology. 71:4014-4021. 2005
- Regulation and function of cytochrome c' in Rhodobacter sphaeroides 2.4.3. Journal of Bacteriology. 187:4077-4085. 2005
- Wiring up single molecules. Thin Solid Films. 438-439:457-461. 2003
- Amperometric TNT biosensor based on the oriented immobilization of a nitroreductase maltose binding protein fusion. Analytical Chemistry. 74:140-148. 2002
- Study of specific binding of maltose binding protein to pyrrole-derived bipyridinium film by quartz crystal microbalance. Langmuir. 18:4892-4897. 2002
- Probing Electrochemical Interfaces With X-Ray Standing Waves. Journal of Physical Chemistry. 90:4926-4928. 1986
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article
- Coulomb blockade and the Kondo effect in single-atom transistors. Nature. 417:722-725. 2002
selected publications listing
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Wang, De-Li; Xin, Huo-Lin L.; Yu, Ying-Chao; Wang, Hong-Sen; Rus, Eric; Muller, David A.; Abruna, Hector D.; “Pt-decorated PdCo@Pd/C core-shell nanoparticles with enhanced stability and electrocatalytic activity for the oxygen reduction reaction”. Journal of the American Chemical Societ,y (2010), 132(50), 17664-17666
Nicholas J. Robertson, Henry A. Kostalik IV, Timothy J. Clark, Paul F. Mutolo, Héctor D. Abruña, and Geoffrey W. Coates “Tunable High Performance Cross-Linked Alkaline Anion-Exchange Membranes for Fuel Cell Applications” JACS, (2010), 132(10) 3400-3404
Deli Wang, Chinmayee V. Subban, Hongsen Wang, Eric Rus, Francis J. DiSalvo, Hector D. Abruña “Highly Stable and CO-tolerant Pt/Ti0.7W0.3O2 Electrocatalyst for Proton Exchange Membrane Fuel Cells” JACS, (2010), 132(30), 10218-10220.
Michael A. Lowe, Yasuyuki Kiya, Jay C. Henderson and Héctor D. Abruña “Pendant thioether polymer fort redox capacitor cathodes” Electrochemistry Communications (2011), 13(5), 462-465.
Burkhardt, Stephen E.; Conte, Sean; Rodriguez-Calero, Gabriel G.; Lowe, Michael A.; Qian, Hualei; Zhou, Weidong; Gao, Jie; Hennig, Richard G.; Abruña, Héctor D.; “Towards organic energy storage: characterization of 2,5-bis(methylthio)thieno[3,2-b]thiophene” Journal of Materials Chemistry (2011), 21(26), 9553-9563
Parks, J. J.; Champagne, A. R.; Costi, T. A.; Shum, W. W.; Pasupathy, A. N.; Neuscamman, E.; Flores-Torres, S.; Cornaglia, P. S.; Aligia, A. A.; Balseiro, C. A.; Chan, G. K.-L.; Abruna, H. D.; Ralph, D. C. “Mechanical Control of Spin States in Spin-1 Molecules and the Underscreened Kondo Effect”. Science (Washington, DC, United States), (2010), 328(5984), 1370-1373.
Wan Li, Cen Tan, Michael A. Lowe, Héctor D. Abruña, and Daniel C. Ralph “Electrochemistry of individual monolayer graphene sheets” ACS Nano (2011 ), 5(3), 2264-2270
presentations
featured in archived article
- Abruña: Different energy solutions for different needs
- Abruña receives two honors for work in electrochemistry
- CU researchers shed light on light-emitting nanodevice
- Cornell researchers develop virus-size 'nanolamps' that could aid use of flexible electronic devices as sensors
- Fuel cells: distant dream, but burning with promise
- New York state funds new battery research at Cornell
- New catalyst of platinum nanoparticles could lead to stall-free, stable fuel cells
- Organic semiconductors make cheap. flexible photovoltaics and LEDs
- Platinum-coated nanoparticles could power fuel cell cars
- Stimulus money will fuel energy research and add jobs
Teaching
teaching activities
Background
education and training
- Ph.D., University of North Carolina, Chapel Hill 1980
- M.S., Rensselaer Polytechnic Institute 1976
- B.S., Rensselaer Polytechnic Institute 1975
educational background
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- PhD, University of North Carolina, Chapel Hill, 1980
- MS, Rensselaer Polytechnic Institute, 1976
- BS, Rensselaer Polytechnic Institute, 1975
awards and honors
- Reilly Award, 2008
awards and distinctions listing
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- Faraday Medal; Electrochemistry Section of the Royal Society, 2011
- Lind Lecturer, 2010
- D. C. Grahame Award from the Electrochemical Society, 2009
- Elected Fellow of the International Society of Electrochemistry, 2008
- C.N. Reilley Award from the Society for Electroanalytical Chemistry; 2008
- Elected Member of the American Academy of Arts and Sciences, 2007
- American Chemical Society Award for Electrochemistry, 2007
- AAAS Fellow 2006-
- Fellow Ecole Normal Superieuere, Paris 2002
- Fellow Ministry of Education and Culture, Spain 2000-2001; 1991-1996
- Honorary Member, Dept. of Chem. Wuhan Univ. Wuhan, PRC 1999 -
- Fellow Generalitat Valenciana 1999-2000
- Iberdrola Fellow 1998-2002
- J. W. Fulbright Senior Fellow 1997
- J. S. Guggenheim Fellow 1992-1993
- Tajima Prize of the International Society of Electrochemistry 1987
- Alfred P. Sloan Fellow 1987 - 1989
- Presidential Young Investigator Award 1984 - 1989
Other
mailing address
- 782A ST Olin, Ithaca, NY 14853